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Diammonium phosphate (DAP)

Diammonium phosphate (DAPIUPAC name diammonium hydrogen phosphate; chemical formula (NH4)2(HPO4)) is one of a series of watersoluble ammonium phosphate salts that can be produced when ammonia reacts with phosphoric acid.

Solid diammonium phosphate shows a dissociation pressure of ammonia as given by the following expression and equation:

(NH4)2HPO4(s) ⇌ NH3(g) + (NH4)H2PO4(s)

At 100 °C, the dissociation pressure of diammonium phosphate is approximately 5 mmHg.

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Diammonium phosphate[1]
Names
IUPAC name

diammonium hydrogen phosphate
Other names

ammonium monohydrogen phosphate, ammonium hydrogen phosphate, ammonium phosphate dibasic
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.079 Edit this at Wikidata
E number E342(ii) (antioxidants, …)
PubChem CID
UNII

Properties
(NH4)2HPO4
Molar mass 132.06 g/mol
Appearance colorless monoclinic crystals
Density 1.619 g/cm3
Melting point 155 °C (311 °F; 428 K) decomposes
57.5 g/100 mL (10 °C)
106.7 g/100 mL (70 °C)
Solubility insoluble in alcoholacetone and liquid ammonia
1.52
Thermochemistry
−1566.91 kJ/mol
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond

Health 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroform Flammability 0: Will not burn. E.g. water Instability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calcium Special hazards (white): no code
Flash point Non-flammable
Safety data sheet (SDS) ICSC 0217
Related compounds
Other anions
Monoammonium phosphate
Triammonium phosphate
Other cations
Disodium phosphate
Dipotassium phosphate
Related compounds
Ammonium nitrate
Ammonium sulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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