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Calcium Hypochlorite

Calcium hypochlorite is an inorganic compound with chemical formula Ca(ClO)2, also written as Ca(OCl)2. It is a white solid, although commercial samples appear yellow. It strongly smells of chlorine, owing to its slow decomposition in moist air. This compound is relatively stable as a solid and solution and has greater available chlorine than sodium hypochlorite. “Pure” samples have 99.2% active chlorine. Given common industrial purity, an active chlorine content of 65-70% is typical. It is the main active ingredient of commercial products called bleaching powder, used for water treatment and as a bleaching agent.

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Calcium hypochlorite
Calcium oxychloride
Names
Other names

  • Hypochlorous acid calcium salt
  • Bleaching powder
  • Chloride of lime
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.029.007 Edit this at Wikidata
EC Number
  • 231-908-7
KEGG
PubChem CID
RTECS number
  • NH3485000
UNII
UN number 1748 2208

Properties
Ca(OCl)2
Molar mass 142.98 g·mol−1
Appearance white/gray powder
Density 2.35 g/cm3 (20 °C)
Melting point 100 °C (212 °F; 373 K)
Boiling point 175 °C (347 °F; 448 K) decomposes
21 g/(100 mL) at 25 °C
Solubility reacts in alcohol
Hazards
GHS labelling:
GHS03: OxidizingGHS05: CorrosiveGHS07: Exclamation markGHS09: Environmental hazard
Danger
H272H302H314H400
P210P220P221P260P264P270P273P280P301+P312P301+P330+P331P303+P361+P353P304+P340P305+P351+P338P310P321P330P363P370+P378P391P405P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond

Health 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gas Flammability 0: Will not burn. E.g. water Instability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calcium Special hazard OX: Oxidizer. E.g. potassium perchlorate
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
850 mg/kg (oral, rat)
Safety data sheet (SDS) ICSC 0638
Related compounds
Other anions
Other cations
Related compounds

 

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