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Boric acid

Boric acid, more specifically orthoboric acid, is a compound of boronoxygen, and hydrogen with formula B(OH)3. It may also be called hydrogen orthoboratetrihydroxidoboron or boracic acid. It is usually encountered as colorless crystals or a white powder, that dissolves in water, and occurs in nature as the mineral sassolite. It is a weak acid that yields various borate anions and salts, and can react with alcohols to form borate esters.

Boric acid is often used as an antisepticinsecticideflame retardantneutron absorber, or precursor to other boron compounds.

The term “boric acid” is also used generically for any oxyacid of boron, such as metaboric acid HBO2 and tetraboric acid H2B4O7.

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Orthoboric acid
Structural formula
Space-filling model
Boric acid crystals
Names
IUPAC name

Boric acid
Other names

Orthoboric acid, Boracic acid, Sassolite, Borofax, Trihydroxyborane, Boranetriol, Hydrogen borate, Acidum boricum
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.030.114 Edit this at Wikidata
EC Number
  • 233-139-2
E number E284 (preservatives)
KEGG
PubChem CID
UNII

Properties
BH3O3
Molar mass 61.83 g·mol−1
Appearance White crystalline solid
Density 1.435 g/cm3
Melting point 170.9 °C (339.6 °F; 444.0 K)
Boiling point 300 °C (572 °F; 573 K)
2.52 g/100 mL (0 °C)
4.72 g/100 mL (20 °C)
5.7 g/100 mL (25 °C)
19.10 g/100 mL (80 °C)
27.53 g/100 mL (100 °C)
Solubility in other solvents Soluble in lower alcohols
moderately soluble in pyridine
very slightly soluble in acetone
log P −0.29
Acidity (pKa) 9.24 (first proton), 12.4 (second), 13.3 (complete)
Conjugate base Borate
−34.1·10−6 cm3/mol
Structure
Trigonal planar
0 D
Pharmacology
S02AA03 (WHOD08AD (WHO)
Hazards
GHS labelling:
GHS08: Health hazard
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond

Health 1: Exposure would cause irritation but only minor residual injury. E.g. turpentine Flammability 0: Will not burn. E.g. water Instability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogen Special hazards (white): no code
Flash point Nonflammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
2660 mg/kg, oral (rat)
Related compounds
Related compounds
Boron trioxide
Borax

Additional information

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