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Ammonium Nitrate

Ammonium nitrate is a chemical compound with the formula NH4NO3. It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, but does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer.

Its other major use is as a component of explosive mixtures used in mining, quarrying, and civil construction. It is the major constituent of ANFO, an industrial explosive which accounts for 80% of explosives used in North America; similar formulations have been used in improvised explosive devices.

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Product Info

Ammonium nitrate
Structural formula
Ammonium nitrate crystal structure
Sample of white powder and spherules
Names
IUPAC name

Ammonium nitrate
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.026.680 Edit this at Wikidata
EC Number
  • 229-347-8
PubChem CID
RTECS number
  • BR9050000
UNII
UN number 0222 – with > 0.2% combustible substances
1942 – with ≤ 0.2% combustible substances
2067 – fertilizers
2426 – liquid

Properties
NH4NO3
Molar mass 80.043 g/mol
Appearance white crystalline solid
Density 1.725 g/cm3 (20 °C)
Melting point 169.6 °C (337.3 °F; 442.8 K)
Boiling point approx. 210 °C (410 °F; 483 K) decomposes
Endothermic
118 g/100 ml (0 °C)
150 g/100 ml (10 °C)
192 g/100 ml (20 °C)
297 g/100 ml (40 °C)
410 g/100 ml (60 °C)
576 g/100 ml (80 °C)
1024 g/100 ml (100 °C)[1]
−33.6×10−6 cm3/mol
Structure
orthorhombic[2]
Explosive data
Shock sensitivity very low
Friction sensitivity very low
Detonation velocity 2500 m/s
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Explosive, Oxidizer
GHS labelling:
GHS07: Exclamation mark GHS03: Oxidizing GHS01: Explosive
Danger
H201H271H319
P220P221P264P271P280P372
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond

Health 1: Exposure would cause irritation but only minor residual injury. E.g. turpentine Flammability 0: Will not burn. E.g. water Instability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxide Special hazard OX: Oxidizer. E.g. potassium perchlorate
Lethal dose or concentration (LD, LC):
LD50 (median dose)
2085–5300 mg/kg (oral in rats, mice)[3]
Related compounds
Other anions
Ammonium nitrite
Other cations
Sodium nitrate
Potassium nitrate
Hydroxylammonium nitrate
Related compounds
Ammonium perchlorate

Additional information

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