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Acrylic Acid

Acrylic acid (IUPACprop-2-enoic acid) is an organic compound with the formula CH2=CHCOOH. It is the simplest unsaturated carboxylic acid, consisting of a vinyl group connected directly to a carboxylic acid terminus. This colorless liquid has a characteristic acrid or tart smell. It is miscible with wateralcoholsethers, and chloroform. More than a million tons are produced annually.

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Product Info

Acrylic acid[1]
Skeletal formula
Ball-and-stick model
Names
IUPAC name

Acrylic acid
Preferred IUPAC name

Prop-2-enoic acid
Other names

  • Acrylic acid
  • Acroleic acid
  • Ethylenecarboxylic acid
  • Propenoic acid
  • Vinylformic acid
  • Methyleneacetic acid
Identifiers
3D model (JSmol)
635743
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.001.071 Edit this at Wikidata
EC Number
  • 201-177-9
1817
KEGG
PubChem CID
RTECS number
  • AS4375000
UNII
UN number 2218

Properties
C3H4O2
Molar mass 72.063 g/mol
Appearance Clear, colorless liquid
Odor Acrid
Density 1.051 g/mL
Melting point 14 °C (57 °F; 287 K)
Boiling point 141 °C (286 °F; 414 K)
Miscible
log P 0.28
Vapor pressure 3 mmHg
Acidity (pKa) 4.25 (H2O)
Viscosity 1.3 cP at 20 °C (68 °F)
Hazards
GHS labelling:
GHS02: FlammableGHS05: CorrosiveGHS07: Exclamation markGHS06: ToxicGHS09: Environmental hazard
Danger
H226H302H312H314H332H400
P210P233P240P241P242P243P260P261P264P270P271P273P280P301+P312P301+P330+P331P302+P352P303+P361+P353P304+P312P304+P340P305+P351+P338P310P312P321P322P330P363P370+P378P391P403+P235P405P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond

Health 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gas Flammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuel Instability 2: Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water. E.g. white phosphorus Special hazards (white): no code
Flash point 49.4 °C (120.9 °F; 322.5 K)
429 °C (804 °F; 702 K)
Explosive limits 2.4–8.02%
NIOSH (US health exposure limits):
PEL (Permissible)
None
REL (Recommended)
TWA 2 ppm (6 mg/m3) [skin]
IDLH (Immediate danger)
N.D.
Safety data sheet (SDS) MSDS
Related compounds
Other anions
acrylate
acetic acid
propionic acid
lactic acid
3-hydroxypropionic acid
malonic acid
butyric acid
crotonic acid
Related compounds
allyl alcohol
propionaldehyde
acrolein
methyl acrylate

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